Abstract The flotation mechanism of galena with xanthate as the collector is generally explained based on the mixed potential of the pulp, in which an anodic electron transfer reaction from the collector to the mineral is combined with an O2 cathodic reduction. Sodium sulphide, often used as a mineral activator, strongly influences the pulp's mixed potential, and depending on the dosage applied, it can become a galena depressor reagent. In this way, the current study assesses galena flotability in the absence of collector, as well as in the presence of the collector potassium amyl xanthate (PAX) and sodium sulphide. The effect of an extremely cathodic potential was also studied through the addition of hydrogen peroxide. In addition, the effect of different stages in the oxidation of the galena surface on the flotability was investigated. Moreover, the zeta potential was measured and contact angle (wettability) tests were carried out. The contact angle measurements were taken for a distilled water, PAX solution and for a mixture of PAX and sodium sulphide solution on the oxidized and non-oxidized surface of galena. All the results showed that galena could be floated in all the PAX concentrations tested. It was observed that a moderate oxidation in the galena surface may contribute to an improvement of its flotation with PAX. However, extremely anodic and cathodic potentials cause flotability close to zero. The zeta potential results showed that sodium sulphide affected the interaction between PAX and galena. The measurements of the contact angle corroborated the results obtained in the microflotation tests. pulp O reduction activator pulps s applied reagent way (PAX peroxide investigated Moreover wettability (wettability out water nonoxidized non tested However zero

Abstract This paper presents the characterization of austenite to pearlite transformation in rail steels (premium and standard) using dilatometry. The critical transformation temperatures were measured as a cooling rate function and the obtained microstructures were qualitatively and quantitatively characterized. Aiming to study the transformation kinetics, three equations proposed by technical literature were evaluated in order to predict the transformation evolution. Experimental and calculated CCT diagrams were compared. It was concluded once the kinetics of phase transformation in rail steels is well characterized, it can be used as reference to enable suitable heat treatment to obtain pearlitic microstructures for the standard steel as refined as those of premium. The minor prior austenite grain size of the standard steel favoured the pearlite nucleation, however its highest Mn, Nb and Si contents delayed the growth stage. All equations evaluated in order to predict the kinetics of austenite to pearlite transformation under continuous cooling were satisfactory.